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Goal
I. Apply the basic principle of ionic and covalent bonding theory. |
Objectives: To meet the requirements of Goal
I, you must be able to:
-
explain the
distinction, on the atomic level, between ionic and covalent molecular
compounds;
-
identify the
electrons in a given element most closely involved in bond formation;
- for
ionic compounds...
-
describe an ionic
bond, and explain the term lattice
energy;
-
use
electron configurations to illustrate the formation of ions and ionic bonds,
and write
chemical formulas for ionic compounds;
-
predict
relative lattice energies for ionic compounds;
-
outline the
sequence of steps in the formation of a binary ionic compound from its
elements (the Born-Haber cycle); name
the chemical change occurring in each step, and give
the name of the energy change associated with each step;
-
use a
Born-Haber cycle with energies known for all steps but one to calculate
the unknown energy;
-
define electronegativity,
and;
-
relate the value for electronegativity assigned to an
element related to its position in the periodic table;
-
use electronegativities to decide
whether a given compound and/or bond is predominantly ionic or covalent;
-
for covalently
bonded elements and compounds...
-
write and interpret Lewis
dot symbols for atoms;
-
combine
Lewis dot symbols for atoms into Lewis structures for covalent molecules
and ions. [Top]
Goal II. Use Lewis dot
structures to deduce molecular shapes and bonding characteristics. |
Objectives: To meet the requirements of Goal
II, you must be able to:
-
use
the electronegativities of two covalently bonded atoms to identify polar
and non-polar covalent bonds;
-
determine the direction
of polarity and compare the degree of polarity among polar covalent bonds;
-
state
the bond order of any bond illustrated by a Lewis structure and
compare bond lengths and bond energies for single, double
and triple bonds;
-
recognize and
write resonance structures
for appropriate molecules and ions;
-
identify and
explain
based on theory the exceptions to the octet rule;
- use
the Valence Shell Electron Pair Repulsion Model (VSEPR)
to predict the shapes of covalently bonded molecules and
ions and to write stereochemical formulas to represent
these three-dimensional molecular shapes;
-
predict polarity
and
identify whether or not a covalently bonded
molecule has a dipole moment, based on its shape. [Top]
Goal III. Use the valence
bond theory of molecular bonding to explain bond formation and observed
properties of covalently bonded species. |
Objectives: To meet the requirements of Goal
III, you must be able to:
-
analyze the structural
formula of a covalently bonded molecule or ion, for:
-
the total number of covalent bonds represented;
-
the number and position of sigma
and
pi bonds;
-
the presence of unshared electron
pairs (lone pairs);
-
understand the
two fundamental concepts of the valence bond model:
-
bond formation by overlap of atomic orbitals;
-
hybridization of atomic orbitals;
-
learn the
sp³d², sp³d, sp³, sp², and sp hybridization; identify the orbitals
involved in sigma bonds and in pi bonds in each of these hybridizations;
-
extend the
concept of orbital hybridization to molecules and ions with a central atom
other than carbon;
- interrelate: Lewis
diagram, VSEPR-derived stereochemical structural formula
hybridization of atomic orbitals, sigma and pi bonding,
bond angles and geometry. [Top]
Unit 9 Assignments |
Read: |
Text
Chapter 9, pp. 340-373
Text Chapter 10,
pp. 377-404
Text Chapter 11,
pp. 410-421 |
Video
Programs: |
- Ionic Bonding
- Covalent Bonding
- Molecular
Geometry VSEPR
- Hybridization
|
Textbook
Assignments: |
Read
and Understand all "Sample Problems," "Follow
Up Problems" and select any 5 blue-colored problems at the
end of the chapters. The
answers for the Follow Up Problems are at the end
of the chapter; the answers for the blue-colored
problems are in Appredix E. |
1. Do Cyber Lab 9
2. Do Cyber 10
|
Submit Cyber Lab 9.
Submit Cyber Lab 10. |
Mandatory ChemSkill Builder Assignments to be submitted for grade (Scores of 80% or higher on each assigned HW section will receive full credit. ) |
Mandatory
assignments to be submitted for grade
Chapter
12.1 Electronegativity, Polarity, 12.2, 12.3, 12.5
Lewis Dot Formulas, shapes, Review of Shapes, Resonance
and Formal Charges NOT Bond Order
Chapter 13, Section
13.1 (Orbital Shapes in molecules)
Chapter
13.2 Valence Bond, Orbital Hybridization, 13.4 Polarity
of molecules |
TAKE
EXAM 5 |
Exam
5 covers Unit 9. |
Note:
Complete Solutions, including all units of measurement,
must be shown for all problems. |
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