Unit 9
Course Guide Chm111

Chemical Bonds and the Chemical Bonding Theory
 

Take Exam 5 after completing this unit.

Goal I
Goal II 
Goal III
Unit 9 Assignments 
Overview
Unit 0
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Unit 6
Unit 7
Unit 8
Unit 9

Goal I. Apply the basic principle of ionic and covalent bonding theory. 

Objectives: To meet the requirements of Goal I, you must be able to:

  1. explain the distinction, on the atomic level, between ionic and covalent molecular compounds; 
  1. identify the electrons in a given element most closely involved in bond formation; 
  1. for ionic compounds...
      1. describe an ionic bond, and explain the term lattice energy;
      2. use electron configurations to illustrate the formation of ions and ionic bonds, and write chemical formulas for ionic compounds;
      3. predict relative lattice energies for ionic compounds;
  1. outline the sequence of steps in the formation of a binary ionic compound from its elements (the Born-Haber cycle); name the chemical change occurring in each step, and give the name of the energy change associated with each step;
  1. use a Born-Haber cycle with energies known for all steps but one to calculate the unknown energy; 
  1. define electronegativity, and; 
      1. relate the value for electronegativity assigned to an element related to its position in the periodic table;
      2. use electronegativities to decide whether a given compound and/or bond is predominantly ionic or covalent;
  1. for covalently bonded elements and compounds... 
      1. write and interpret Lewis dot symbols for atoms;
      2. combine Lewis dot symbols for atoms into Lewis structures for covalent molecules and ions. [Top]

Goal II. Use Lewis dot structures to deduce molecular shapes and bonding characteristics.

Objectives: To meet the requirements of Goal II, you must be able to:

  1. use the electronegativities of two covalently bonded atoms to identify polar and non-polar covalent bonds;
  1. determine the direction of polarity and compare the degree of polarity among polar covalent bonds; 
  1. state the bond order of any bond illustrated by a Lewis structure and compare bond lengths and bond energies for single, double and triple bonds;
  1. recognize and write resonance structures for appropriate molecules and ions; 
  1. identify and explain based on theory the exceptions to the octet rule
  1. use the Valence Shell Electron Pair Repulsion Model (VSEPR) to predict the shapes of covalently bonded molecules and ions and to write stereochemical formulas to represent these three-dimensional molecular shapes;
  1. predict polarity and identify whether or not a covalently bonded molecule has a dipole moment, based on its shape. [Top] 


Goal III. Use the valence bond theory of molecular bonding to explain bond formation and observed properties of covalently bonded species.

Objectives: To meet the requirements of Goal III, you must be able to: 

  1. analyze the structural formula of a covalently bonded molecule or ion, for: 
      1. the total number of covalent bonds represented;
      2. the number and position of sigma and pi bonds;
      3. the presence of unshared electron pairs (lone pairs);
  1. understand the two fundamental concepts of the valence bond model: 
      1. bond formation by overlap of atomic orbitals;
      2. hybridization of atomic orbitals;
  1. learn the sp³d², sp³d, sp³, sp², and sp hybridization; identify the orbitals involved in sigma bonds and in pi bonds in each of these hybridizations;
  1. extend the concept of orbital hybridization to molecules and ions with a central atom other than carbon; 
  1. interrelate: Lewis diagram, VSEPR-derived stereochemical structural formula hybridization of atomic orbitals, sigma and pi bonding, bond angles and geometry. [Top] 

Unit 9 Assignments
Read: Text Chapter 9, pp. 340-373
Text Chapter 10, pp. 377-404
Text Chapter 11, pp. 410-421
Video Programs:
  1. Ionic Bonding
  2. Covalent Bonding
  3. Molecular Geometry VSEPR
  4. Hybridization
Textbook Assignments: Read and Understand all "Sample Problems," "Follow Up Problems" and select any 5 blue-colored problems at the end of the chapters.

The answers for the Follow Up Problems are at the end of the chapter; the answers for the blue-colored problems are in Appredix E.

1. Do Cyber Lab 9

2. Do Cyber 10

Submit Cyber Lab 9.

Submit Cyber Lab 10.

Mandatory ChemSkill Builder Assignments to be submitted for grade (Scores of 80% or higher on each assigned HW section will receive full credit. ) Mandatory assignments to be submitted for grade

Chapter 12.1 Electronegativity, Polarity, 12.2, 12.3, 12.5 Lewis Dot Formulas, shapes, Review of Shapes, Resonance and Formal Charges NOT Bond Order 
Chapter 13, Section 13.1 (Orbital Shapes in molecules)
Chapter 13.2 Valence Bond, Orbital Hybridization, 13.4 Polarity of molecules

TAKE EXAM 5 Exam 5 covers Unit 9.
Note: Complete Solutions, including all units of measurement, must be shown for all problems.

[Top]


Overview
Unit 0
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Unit 6
Unit 7
Unit 8
Unit 9