flasks and beakers

  Unit 1
Course Guide CHM 112
 
 
 

Liquids and Solids

Goal I 
Goal II
Goal III
Goal IV
Unit 1 Assignments
Overview
Unit 0
Unit 1
Unit 2
Unit 3
Unit 4
Unit 6

Goal I.  Apply the kinetic-molecular theory to physical properties of solids and liquids. 

Objectives: To meet the requirements of Goal I, you must be able to:

  1. describe and compare:
    • the volume-shape characteristics and relative densities of solids, liquids and gases;
    • amorphous and crystalline solids;
    • the relative compressibilities of solids, liquids and gases.
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Goal II. Develop an understanding of intermolecular forces.

Objectives: To meet the requirements of Goal II, you must be able to:

  1. distinguish between intermolecular attractions and intramolecular attractions (chemical bonds).
  1. compare the relative strengths of inter- and intra-molecular forces in terms of the energies necessary to overcome these forces.
  1. distinguish between ion-ion attractions and dipole-dipole interactions.
  1. explain the origin of dipole-dipole forces and recognize, from chemical formulas and a knowledge of molecular geometry,  compounds in which dipole-dipole forces exist between constituent molecules.
  1. identify from chemical formula compounds in which dipole-dipole forces called hydrogen bonds exist between constituent molecules.
  1. explain the origin of London dispersion forces and recognize from chemical formula those substances (compounds or elements) in which only London forces exist between constituent molecules (compounds) or atoms (elements). Understand "polarizability" and predict trends in "polarizability" across a period and down a group.
  1. compare the relative strengths of intermolecular London dispersion attractions between molecules of different compounds based on:
    • molecular shape (geometry);
    • size (volume occupied);
    • mass.
  1. compare the relative importance of dipole-dipole and London dispersion attractions.
  2. describe the properties of viscosity, surface tension and capillary action and relate these properties to intermolecular attractions between molecules and to temperature.
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Goal III. Understand the physical properties of liquids applying kinetic-molecular theory and a knowledge of intermolecular attractions.

Objectives: To meet the requirements of Goal III, you must be able to:

  1. explain the process of evaporation in terms of the kinetic-molecular theory.
  2. describe the state of dynamic equilibrium established between a liquid and its vapor confined to a closed container.
  3. explain the effect of temperature changes on an established liquid-vapor equilibrium in terms of:
    • the rates of condensation and vaporization;
    • the number of particles in the liquid and in the vapor states;
    • a shifting of equilibrium.
  1. define equilibrium vapor pressure of a liquid and describe its dependence on:
    • intermolecular attractions between the liquid's constituent particles;
    • temperature of the system; understand and use the Clausius Clapeyron Equation to understand the relationship between temperature, vapor pressure and the heat of vaporization
    • amount of liquid present.
  2. define normal boiling point and predict relative normal boiling points of different liquids based on a knowledge of the existing intermolecular attractions in the liquids.
  3. explain the effect of external pressure on the actual boiling point of a liquid.
  4. define normal melting point and contrast this to the freezing point of a substance.
  5. describe the roles of energy and entropy in the equilibrium established between a liquid and its melt at the freezing point.
  6. interpret a heating or cooling curve by:
    • defining the terms used to describe the thermal energies involved for each region of the curve;
    • explaining the slope of the curve and the phases present within each region;
    • calculating energy involved in melting, freezing, boiling, condensing or heating a given mass of substance.
  1. interpret a phase diagram by:
    • defining the terms: supercritical fluid, critical point, triple point, critical temperature, critical pressure, sublimation, deposition;
    • relating the slope of the liquid-solid equilibrium line to the relative densities of the liquid and solid phases;
    • predicting the stable phase or phases in equilibrium at a given temperature-pressure.
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Goal IV. Develop a basic knowledge of the nature of the solid state.

Objectives: To meet the requirements of Goal IV, you must be able to:

  1. distinguish among and give example of atomic, molecular, ionic, covalent network and metallic crystals on the basis of:
    • constituent particles (units);
    • forces between units;
    • properties.
  2. describe the simple cubic, face-centered cubic, and body-centered cubic packing arrangements.
  3. define conductor, semiconductor, superconductor and insulator (non-conductor). Understand the effect of temperature on the conductivity of conductors, semiconductors, superconductors. Understand the Molecular Orbital Bend Theory, and explain the difference in electrical conductivity of conductors, semiconductors, superconductors, and insulators. Distinguish between n-type and p-type semiconductors.
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Unit 1 Assignments
Objectives 1 through 10
Read Text:
View Video programs:
Chapter 12: pp.436-448
1.   Kinetic molecular theory and IMF
2.   IMF and physical properties of solutions
Objectives 11 through 23
Text:
Video Programs:
Chapter 12: pp.425-436; 449-465
3.   Phase diagrams and phase changes
4.   Heating and cooling curves
5.   The solid state
Textbook Assignments: Read and Understand all "Sample Problems," "Follow Up Problems" and select any 5 blue-colored problems at the end of the chapters.

The answers to the Follow Up Problems are at the end of each chapter; the answers to the blue-colored problems are in Appendix E.

Mandatory ChemSkill Builder Assignments to be submitted for grade (Scores of 80% or higher on each assigned HW section will receive full credit. ) Chapter 14.1, 14.2, 14.3, 14.4, 14.5, 14.6 Liquids and Solids;
Lab Assignments
  • Read Lab Manual pp. 1-40
  • Go to Blackboard Assignments area to complete LSOT
  • Take the proctored online Lab Safety Quiz
  • Take the proctored online Nomenclature Test

Nomenclature:

  1. read textbook pages 62-68
  2. read lab manual pages 128 – 135
  3. read lab guide pages 13- 28
  • Do Cyber Lab 11, record the data and then answer the questions (See CHM 111 Laboratory Guide and Cyber-Chem CD Disk #1.)
  • Submit the report in Blackboard Assignments area
Take Exam: (The score will not be dropped.) Exam 1
Note: Complete Solutions, including all units of measurement, must be done for all problems.

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Overview
Unit 0
Unit 1
Unit 2
Unit 3
Unit 4
Unit 6