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Goal
I. Apply the kinetic-molecular theory to physical properties of solids
and liquids. |
Objectives: To meet the requirements of Goal
I, you must be able to:
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describe and
compare:
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the volume-shape characteristics and relative
densities of solids, liquids and gases;
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amorphous and crystalline solids;
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the relative compressibilities of solids,
liquids and gases.
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Goal II. Develop an understanding
of intermolecular forces. |
Objectives: To meet the requirements of Goal
II, you must be able to:
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distinguish between intermolecular
attractions and intramolecular attractions (chemical bonds).
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compare the relative
strengths of inter- and intra-molecular forces in terms of the energies
necessary to overcome these forces.
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distinguish between ion-ion
attractions and dipole-dipole interactions.
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explain the
origin of dipole-dipole forces and recognize, from chemical formulas and
a knowledge of molecular geometry, compounds in which dipole-dipole
forces exist between constituent molecules.
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identify from
chemical formula compounds in which dipole-dipole forces called hydrogen
bonds exist between constituent molecules.
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explain
the origin of London dispersion forces and recognize from chemical formula
those substances (compounds or elements) in which only London forces
exist between constituent molecules (compounds) or atoms (elements). Understand "polarizability" and predict trends in "polarizability" across a period and down a group.
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compare
the relative strengths of intermolecular London dispersion attractions
between molecules of different compounds based on:
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molecular shape (geometry);
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size (volume occupied);
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mass.
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compare
the relative importance of dipole-dipole and London dispersion attractions.
- describe the properties of viscosity, surface tension and capillary action and relate these properties to intermolecular attractions between molecules and to
temperature.
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Goal III. Understand the
physical properties of liquids applying kinetic-molecular theory and a
knowledge of intermolecular attractions. |
Objectives: To meet the requirements of Goal
III, you must be able to:
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explain the process
of evaporation in terms of the kinetic-molecular theory.
- describe the state
of dynamic equilibrium established between a liquid and its vapor
confined to a closed container.
- explain
the effect of temperature changes on an established liquid-vapor equilibrium
in terms of:
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the rates of condensation and vaporization;
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the number of particles in the liquid and in the vapor
states;
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a shifting of equilibrium.
- define equilibrium
vapor pressure of a liquid and describe
its dependence on:
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intermolecular attractions between the liquid's constituent
particles;
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temperature of the system; understand and use the Clausius Clapeyron Equation to understand the relationship between temperature, vapor pressure and the heat of vaporization
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amount of liquid present.
- define normal
boiling point and predict relative
normal boiling points of different liquids based on a knowledge of the
existing intermolecular attractions in the liquids.
- explain the effect
of external pressure on the actual boiling point of a liquid.
- define normal
melting point and contrast this
to the freezing point of a substance.
- describe the roles
of energy and entropy in the equilibrium established between a liquid and
its melt at the freezing point.
- interpret a heating
or cooling curve by:
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defining the terms used to describe the thermal energies
involved for each region of the curve;
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explaining the slope of the curve and the phases present
within each region;
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calculating energy involved in melting, freezing, boiling,
condensing or heating a given mass of substance.
- interpret a phase
diagram by:
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defining the terms: supercritical fluid, critical point,
triple point, critical temperature, critical pressure, sublimation, deposition;
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relating the slope of the liquid-solid equilibrium line
to the relative densities of the liquid and solid phases;
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predicting the stable phase or phases in equilibrium
at a given temperature-pressure.
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Goal IV. Develop a basic
knowledge of the nature of the solid state. |
Objectives: To meet the requirements of Goal
IV, you must be able to:
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distinguish among
and give example of atomic, molecular, ionic, covalent network and metallic crystals on the basis of:
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constituent particles (units);
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forces between units;
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properties.
- describe the simple cubic, face-centered cubic, and body-centered cubic packing
arrangements.
- define conductor, semiconductor, superconductor and insulator (non-conductor). Understand the effect of temperature on the conductivity of conductors, semiconductors, superconductors. Understand the Molecular Orbital Bend Theory, and explain the difference in electrical conductivity of conductors, semiconductors, superconductors, and insulators. Distinguish between n-type and
p-type semiconductors.
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Unit 1 Assignments |
Objectives
1 through 10
Read Text:
View Video
programs: |
Chapter 12: pp.436-448
1. Kinetic molecular theory
and IMF
2. IMF and physical properties
of solutions |
Objectives
11 through 23
Text:
Video Programs: |
Chapter
12: pp.425-436; 449-465
3. Phase diagrams and
phase changes
4. Heating and cooling
curves
5. The solid state |
Textbook
Assignments: |
Read
and Understand all "Sample Problems," "Follow Up Problems" and select any 5 blue-colored problems at the end of the chapters.
The answers
to the Follow Up Problems are at the end of each chapter; the answers to
the blue-colored problems are in Appendix E. |
Mandatory
ChemSkill
Builder Assignments to
be submitted for grade (Scores of 80% or higher on each assigned HW section will receive full credit. ) |
Chapter
14.1,
14.2,
14.3,
14.4,
14.5,
14.6 Liquids and Solids; |
Lab Assignments |
- Read Lab Manual pp. 1-40
- Go to Blackboard Assignments area to complete LSOT
- Take the proctored online Lab Safety Quiz
- Take the proctored online Nomenclature Test
Nomenclature:
- read textbook pages 62-68
- read lab manual pages 128 – 135
- read lab guide pages 13- 28
- Do Cyber Lab 11, record the data and then answer the questions (See CHM 111 Laboratory Guide and Cyber-Chem CD Disk #1.)
- Submit the report in Blackboard Assignments area
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Take Exam: (The score
will not be dropped.) |
Exam 1 |
Note: Complete
Solutions, including all units of measurement, must be done for all problems. |
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