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  Unit 7
Course Guide Chm111

Atomic Structure

Goal I
Goal II 
Goal III
Unit 7 Assignments
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Goal I. Describe some of the experimental and theoretical developments leading to the quantum mechanical model of the atom.

Objectives: To meet the requirements of Goal I, you must be able to:

  1. describe briefly the sequence of experiments and analysis which led to the model for atomic structure used by chemists;
  1. define electromagnetic radiation, wavelength, frequency, amplitude, cycle, node, photon; 
  1. convert among energy, wavelength and/or frequency of a photon;
  1. describe the electromagnetic radiation spectrum, including relative energies, wavelengths and frequencies of its various "regions"; 
  1. relate the colors in the visible region of the spectrum to the energies of photons. [Top]

Goal II. Describe and apply the features of the Bohr model of the hydrogen atom to atomic structure and electronic spectra.

Objectives: To meet the requirements of Goal II, you must be able to:

  1. distinguish between emission spectrum and absorption spectrum of an element;
  1. describe the Bohr model of the hydrogen atom and how it was used to explain the atomic emission spectrum of hydrogen; 
  1. explain the statement, " The energy of the hydrogen atom is quantized;
  1. use Equations 7.3 (p. 267) and 7.4 (p. 267) to calculate the difference in energies of any pair of principal quantum levels and relate this difference to the wavelength (or frequency) of an associated spectral line;
  1. explain why Bohr's model of the hydrogen atom was abandoned in favor of the wave mechanical model for atomic structure. [Top] 


Goal III. Using the wave mechanical model, explain the fundamental concepts regarding electron arrangement in atoms.

Objectives: To meet the requirements of Goal III, you must be able to: 

  1. describe the interpretation given to the wave function (y) and of the square of a wave function (y²) , in Schrödinger's wave mechanical model of the hydrogen atom; 
  1. interpret the quantum numbers n, l, ml; which appear in the mathematical solution to the Schrödinger equation describing the behavior and energies of electrons in atoms;
  1. state the Heisenberg Uncertainty Principle, and the Pauli Exclusion Principle and explain their implications for determining the electronic structure of an atom;
  1. explain the following terms used in the wave mechanical model of the atom: orbital, shell subshell, radial distribution function, boundary surface; 
  1. interpret the spin quantum number, ms, and relate this quantum number to the Pauli Exclusion Principle; 
  1. know and be able to use the information in Table 7.4 (p. 279) including: 
      1. the allowed combinations of quantum numbers for "shells" n=1-4,
      2. the letter used to designate "subshells" defined by the angular momentum quantum number "l";
  1. know the boundary surface diagrams for s, p, and d type orbitals; 
  1. determine the number of orbitals in a shell or subshell, and determine the number of electrons that can occupy a shell or a subshell in a many-electron atom. [Top] 

Unit 7 Assignments
Read: Text Chapter 7, pp. 259-285
Video Programs:
  1. Light and Matter, Electromagnetic Radiation
  2. Aufbau Principle, Wave Mechanical Model
Textbook Assignments: Read and Understand all "Sample Problems," "Follow Up Problems" and the blue-colored problems at the end of the chapters.

The answers for the Follow Up Problems are at the end of the chapter; the answers for the blue-colored problems are in Appendix C.The answers for each of these are in Appendix C.

ChemSkill Builder Assignments: Mandatory assignments to be submitted for grade

Chapter 9, Sections  9.2, 9.6  (Light and Energy, quantum numbers)

Note: Complete Solutions, including all units of measurement, must be shown for all problems.
Select and complete Optional Lab: See CHM 111 Laboratory Guide. Submit via mail to ELI.

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Overview
Unit 0
Unit 1
Unit 2
Unit 3
Unit 4
Unit 5
Unit 6
Unit 7
Unit 8
Unit 9

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