flasks and beakers

 

  Unit 8
Course Guide Chm111

Electronic Structure and the Periodic Table
 
 

Take Exam 4 after completing this unit.

Goal I
Goal II
Unit 8 Assignments 
Periodic Table Practice Sheet
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Goal I. Predict the electron configuration of atoms and ions by reference to the periodic table of the elements.

Objectives: To meet the requirements of Goal I, you must be able to:

  1. describe the major differences between orbital energies for the hydrogen atom (Fig. 7.20) and for atoms with more than one electron (Fig. 8.4)
  1. use the concepts of shielding and effective nuclear charge to explain the observations: 
      1. in an atom with more than one electron, electrons in different subshells within the same shell have different energies;
      2. in atoms of different elements, electrons in the same subshell have different energies; 
  1. describe the Aufbau approach to determining electron configuration;
  1. define the term degenerate as it applies to orbitals within an atom;
  1. state and apply Hund's Rule; recognize paramagnetic and diamagnetic electron configurations;
  1. write, for an atom in its ground state or in a specified excited state, the following: 
      1. an abbreviated electron configuration using core notation,
      2. an orbital diagram; (p. 299)
  1. identify on the periodic table: 
      1. s,p,d, and f block elements
      2. main group elements, first, second, and third transition series; lanthanide and actinide series;
  1. use the periodic table to predict the valence shell electron configurations in atoms of main group elements and first row transition elements; 
  1. predict charges on ions formed by main group elements; write ground state electron configurations for ions with specified charges; 
  1. distinguish the ground state electronic configuration of an atom or ion from an excited state configuration; 
  1. identify isoelectronic atoms and ions.[Top] 

Goal II. Relate periodic trends in electron configuration to properties of elements.

Objectives: To meet the requirements of Goal II, you must be able to:

  1. relate trends in atomic radii within groups and across periods to electron configurations; compare relative sizes of atoms and their ions;
  1. relate trends in the first ionization energies of elements within groups and across periods to electron configurations
  1. relate the relative magnitudes of successive ionization energies for an element to the electronic configuration of its atoms; 
  1. relate trends of electron affinities of elements within groups and across periods to electron configurations;
  1. explain the significance of a negative value for electron affinity; 
  1. discuss the major distinguishing chemical characteristics of hydrogen, the alkali metals, the alkaline-earth metals, halogens, transition metals, actinides and lanthanides, and noble gases and relate these characteristics to electron configurations.[Top] 

Unit 8 Assignments
Read: Text Chapter 8, pp. 292-325
Video Programs:
  1. Aufbau Principle
  2. Electron Configuration and Periodic Table
Textbook Assignments: Read and Understand all "Sample Problems," "Follow Up Problems" and the blue-colored problems at the end of the chapters.

The answers for the Follow Up Problems are at the end of the chapter; the answers for the blue-colored problems are in Appendix C.The answers for each of these are in Appendix C.

ChemSkill Builder Assignments: Mandatory assignments to be submitted for grade

Chapter 9, Sections 9.3, 9.4, 9.5 (box orbital diagrams, electron configuration I & II) 
Chapter 11, Sections 11.1, 11.2 (size of atoms and ions, ionization energy, electron affinity)

TAKE EXAM 4:  Exam 4 covers Units 7 and 8. You will be given a copy of the Periodic Table.

You may use a 3" x 5" hand-written study card for Exams 1, 2, 3, 4, and 5. (NOT TO BE USED FOR THE NOMENCLATURE TEST.) You must hand-write the information you would like to have on your card yourself -- no technology miracles allowed. Formulas, constants, definitions, concepts, solubility tables, etc., may be on the study card. NO SAMPLE PROBLEMS are allowed to be on the card. You may write on both sides of the study card. The card must be submitted with your exam. Any abuse of this privilege will result in a failing grade for the course.

Note: Complete Solutions, including all units of measurement, must be shown for all problems.

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